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4238703 
Journal Article 
Cu-Catalyzed Stereoselective Borylation of gem-Difluoroalkenes with B2pin2 
Zhang, J; Dai, W; Liu, Q; Cao, S 
2017 
1 
Organic Letters
ISSN: 1523-7060
EISSN: 1523-7052 
19 
12 
3283-3286 
English 
28581762 
A novel and efficient method for the synthesis of (Z)-fluorinated alkenylboronic acid pinacol esters via Cu-catalyzed stereoselective borylation of gem-difluoroalkenes using bis(pinacolato)diboron (B2pin2) as the boron source with the assistance of NaOtBu and Xantphos at room temperature was developed. 
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