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HERO ID
4455300
Reference Type
Journal Article
Title
Temporal viscosity modulations driven by a pH sensitive polymer coupled to a pH-changing chemical reaction
Author(s)
Escala, DM; Muñuzuri, AP; De Wit, A; Carballido-Landeira, J
Year
2017
Is Peer Reviewed?
1
Journal
Physical Chemistry Chemical Physics
ISSN:
1463-9076
EISSN:
1463-9084
Volume
19
Issue
19
Page Numbers
11914-11919
Language
English
PMID
28440385
DOI
10.1039/c7cp00426e
Web of Science Id
WOS:000401640600020
Abstract
The Formaldehyde-Sulfite (FS) and the Formaldehyde-Sulfite-Gluconolactone (FSG) systems are examples of complex chemical reactions accompanied by well-controlled variations in pH. While the FS system exhibits a clock behavior, in the FSG reaction, this mechanism is coupled with the hydrolysis of the gluconolactone which gives the possibility to show large temporal oscillations of pH in an open reactor. In this work, we show how these reactive systems, due to their organic nature, can be coupled with pH sensitive polymers, particularly with polyacrylic acid (PAA) to trigger temporal changes of viscosity. We characterize this coupled reactive system showing the effects of changes in the initial concentrations of the polymer and in the chemical reagents on the induction time, the magnitude of the pH variations and the temporal modifications of the viscosity.
Tags
IRIS
•
Formaldehyde
HAWC
Nervous system
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Nervous system effects
PubMed
2017-2018 LitSearch
Nervous System Effects
Pubmed
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Pulmonary Function
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OPPT
•
Gluconates
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PubMed (private)
Fate
WOS (private)
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