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HERO ID
48185
Reference Type
Journal Article
Title
Observations of near-zero ozone concentrations over the convective Pacific: Effects on air chemistry
Author(s)
Kley, D; Crutzen, PJ; Smit, HGJ; Vomel, H; Oltmans, SJ; Grassl, H; Ramanathan, V
Year
1996
Is Peer Reviewed?
1
Journal
Science
ISSN:
0036-8075
EISSN:
1095-9203
Volume
274
Issue
5285
Page Numbers
230-233
DOI
10.1126/science.274.5285.230
Web of Science Id
WOS:A1996VM67100038
URL
http://www.sciencemag.org/cgi/doi/10.1126/science.274.5285.230
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Abstract
A series of measurements over the equatorial Pacific in March 1993 showed thai the volume mixing ratios of ozone were frequently well below 10 nanomoles per mole both in the marine boundary layer (MEL) and between 10 kilometers and the tropopause. These latter unexpected results emphasize the enormous variability of tropical tropospheric ozone and hydroxyl concentrations, which determine the oxidizing efficiency of the trophosphere. They also imply a convective short circuit of marine gaseous emissions, such as dimethyl sulfide, between the MBL and the uppermost troposphere, leading, for instance, to sulfate particle formation.
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NAAQS
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ISA-NOx (2016)
2008 Final
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