CONFORMATIONAL-ANALYSIS AND ELECTROMAGNETIC PROPERTIES OF 1,1,2-TRIBROMO-2-PHENYLETHANE | Health & Environmental Research Online (HERO)

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HERO ID

5095258

Reference Type

Journal Article

Title

CONFORMATIONAL-ANALYSIS AND ELECTROMAGNETIC PROPERTIES OF 1,1,2-TRIBROMO-2-PHENYLETHANE

Author(s)

Vulfson, SG; Dianova, OM; Kataev, VE; Vereshchagin, AN

Year

1987

Is Peer Reviewed?

Journal

Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230

Volume

Issue

Page Numbers

1209-1213

Language

English

DOI

10.1007/BF00956664

Web of Science Id

WOS:A1987L848600023

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250104663&doi=10.1007%2fBF00956664&partnerID=40&md5=9b6817798b4348f53817cc09fd6b60ef
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Abstract

1. In CCl4, the molecules of 1,1,2-tribromo-2-phenylethane coexist in the form of three rotational isomers with the predominance (by 2/3) of the form with the trans disposition of the C-H bonds; the most polar G2-conformer comprises a minor amount (<-5%). 2. In the trans and gauche retainers, the angles of rotation of the phenyl do not depend on the orientation of the vicinal C-Br bonds. © 1987 Plenum Publishing Corporation.