Gas chromatographic enantiomer separation of some selected polycyclic xenobiotics using modified cyclodextrins

Koske, G; Leupold, G; Parlar, H

HERO ID

2170999

Reference Type

Journal Article

Year

1997

HERO ID 2170999
In Press No
Year 1997
Title Gas chromatographic enantiomer separation of some selected polycyclic xenobiotics using modified cyclodextrins
Authors Koske, G; Leupold, G; Parlar, H
Journal Fresenius Environmental Bulletin
Volume 6
Issue 7-8
Page Numbers 489-493
Abstract The enantiomers of several polychlorinated xenobiotics (heptachlor, cis- and trans-chlordane, trans- and cis-heptachlorepoxide, oxychlordane, photo-heptachlor and photo-heptachlor-epoxide, photo-dieldrin, photo-chlordene, alpha-HCH, o,p'-DDT and o,p'-DDD) have been separated by gas chromatography with three beta-cyclodextrin derivatives as chiral selectors. Two of these selectors were dissolved in a polysiloxane stationary phase and one was chemically bonded to a polysiloxane backbone via hydrosilylation. The order of elution of some of the xenobiotics was determined by comparison with enantiomerically enriched reference compounds.
Wosid WOS:A1997XJ34100022
Is Certified Translation No
Dupe Override No
Is Public Yes
Keyword enantioselective gas chromatography; cyclodextrine derivatives; polychlorinated pesticides; cyclodiene photoconversion products