Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
4729980
Reference Type
Journal Article
Title
The effect of polymer aging on the uptake of fuel aromatics and ethers by microplastics
Author(s)
Müller, A; Becker, R; Dorgerloh, U; Simon, FG; Braun, U
Year
2018
Is Peer Reviewed?
Yes
Journal
Environmental Pollution
ISSN:
0269-7491
EISSN:
1873-6424
Volume
240
Page Numbers
639-646
Language
English
PMID
29772514
DOI
10.1016/j.envpol.2018.04.127
Web of Science Id
WOS:000438322100070
URL
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85048536822&doi=10.1016%2fj.envpol.2018.04.127&partnerID=40&md5=18454ee6456951947a875e309a262673
Exit
Abstract
Microplastics are increasingly entering marine, limnic and terrestrial ecosystems worldwide, where they sorb hydrophobic organic contaminants. Here, the sorption behavior of the fuel-related water contaminants benzene, toluene, ethyl benzene and xylene (BTEX) and four tertiary butyl ethers to virgin and via UV radiation aged polypropylene (PP) and polystyrene (PS) pellets was investigated. Changes in material properties due to aging were recorded using appropriate polymer characterization methods, such as differential scanning calorimetry, Fourier transform infrared spectroscopy, gel permeation chromatography, X-ray photoelectron spectroscopy, and microscopy. Pellets were exposed to water containing BTEX and the ethers at 130-190 μg L-1 for up to two weeks. Aqueous sorbate concentrations were determined by headspace gas chromatography. Sorption to the polymers was correlated with the sorbate's Kow and was significant for BTEX and marginal for the ethers. Due to substantially lower glass transition temperatures, PP showed higher sorption than PS. Aging had no effect on the sorption behavior of PP. PS sorbed less BTEX after aging due to an oxidized surface layer.
Tags
•
Ethylbenzene
New Litsearch 4/2019
PubMed
Toxline
WOS
Litsearch Update April 2023
SCOPUS
•
PCBs
Not prioritized for screening
Litsearches
Litsearch: Aug 2017 - Aug 2018
PubMed
Not prioritized for screening
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity