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2064217 
Journal Article 
Stabilization of tetrahedral P4 and As4 molecules as guests in polymeric and spherical environments 
Schwarzmaier, C; Schindler, A; Heindl, C; Scheuermayer, S; Peresypkina, EV; Virovets, AV; Neumeier, M; Gschwind, R; Scheer, M 
In Press 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
52 
41 
10896-10899 
English 
As you like it: [Ag(η(2) -As4 )2 ](+) [pftb](-) can be used to store yellow arsenic (As4 ). From it, As4 can be easily released to give concentrated, light-stable solutions. These As4 solutions, and those of white phosphorus (P4 ), allowed molecular As4 and P4 to be encapsulated inside giant, spherical aggregates and polymeric matrices, enabling the first determination of their EE (E=P, As) bond lengths by diffraction methods. 
arsenic; host-guest chemistry; phosphorus; structure determination; supramolecular chemistry 
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